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Manuel
Bernard Ghislain Lartigue Guillaume Balarac Vincent Moureau Guillaume Puigt 《国际流体数值方法杂志》2020,92(11):1551-1583
In this article, a new framework to design high-order approximations in the context of node-centered finite volumes on simplicial meshes is proposed. The major novelty of this method is that it relies on very simple and compact differential operators, which is a critical point to achieve good performances in the High-performance computing context. This method is based on deconvolution between nodal and volume-average values, which can be conducted to any order. The interest of the new method is illustrated through three different applications: mesh-to-mesh interpolation, levelset curvature computation, and numerical scheme for convection. Higher order can also be achieved within the present framework by introducing high-rank tensors. Although these tensors feature much symmetries, their manipulation can quickly become an overwhelming task. For this reason and without loss of generality, the present articles are limited to third-order expansion. This method, although tightly connected to the k-exact schemes theory, does not rely on successive corrections: the high-order property is obtained in a single operation, which makes them more attractive in terms of performances. 相似文献
3.
Dennis Weidener Kawarpal Singh Bernhard Blümich 《Magnetic resonance in chemistry : MRC》2019,57(10):852-860
For optimization and control of pharmaceutically and industrially important reactions, chemical information is required in real time. Instrument size, handling, and operation costs are important criteria to be considered when choosing a suitable analytical method apart from sensitivity and resolution. This present study explores the use of a robust and compact nuclear magnetic resonance (NMR) spectrometer to monitor the stereo-selective formation of α-fluoro-α,β-unsaturated esters from α-fluoro-β-keto esters via deprotonation and deacylation in real time. These compounds are precursors of various pharmaceutically active substances. The real-time study revealed the deprotonation and deacylation steps of the reaction. The reaction was studied at temperatures ranging from 293 to 333 K by interleaved one-dimensional 1H and 19F and two-dimensional 1H–1H COSY experiments. The kinetic rate constants were evaluated using a pseudo first-order kinetic model. The activation energies for the deprotonation and deacylation steps were determined to 28 ± 2 and 63.5 ± 8 kJ/mol, respectively. This showed that the deprotonation step is fast compared with the deacylation step and that the deacylation step determines the rate of the overall reaction. The reaction was repeated three times at 293 K to monitor the repeatability and stability of the system. The compact NMR spectrometer provided detailed information on the mechanism and kinetics of the reaction, which is essential for optimizing the synthetic routes for stepwise syntheses of pharmaceutically active substances. 相似文献
4.
Shai Shechter 《Journal of Pure and Applied Algebra》2019,223(10):4384-4425
Let be a complete discrete valuation ring with finite residue field of odd characteristic, and let G be a symplectic or special orthogonal group scheme over . For any let denote the ?-th principal congruence subgroup of . An irreducible character of the group is said to be regular if it is trivial on a subgroup for some ?, and if its restriction to consists of characters of minimal -stabilizer dimension. In the present paper we consider the regular characters of such classical groups over , and construct and enumerate all regular characters of , when the characteristic of is greater than two. As a result, we compute the regular part of their representation zeta function. 相似文献
5.
《Mathematische Nachrichten》2017,290(14-15):2308-2321
Let be a Banach operator ideal and X be a Banach space. We undertake the study of the vector space of ‐null sequences of Carl and Stephani on X , , from a unified point of view after we introduce a norm which makes it a Banach space. To give accurate results we consider local versions of the different types of accessibility of Banach operator ideals. We show that in the most common situations, when is right‐accessible for , behaves much alike . When this is the case we give a geometric tensor product representation of . On the other hand, we show an example where the representation fails. Also, via a trace duality formula, we characterize the dual space of . We apply our results to study some problems related with the ‐approximation property giving a trace condition which is used to solve the remaining case () of a problem posed by Kim (2015). Namely, we prove that if a dual space has the ‐approximation property then the space has the ‐approximation property. 相似文献
6.
Mixed two‐grid finite difference methods for solving one‐dimensional and two‐dimensional Fitzhugh–Nagumo equations 下载免费PDF全文
The aim of this paper is to propose mixed two‐grid finite difference methods to obtain the numerical solution of the one‐dimensional and two‐dimensional Fitzhugh–Nagumo equations. The finite difference equations at all interior grid points form a large‐sparse linear system, which needs to be solved efficiently. The solution cost of this sparse linear system usually dominates the total cost of solving the discretized partial differential equation. The proposed method is based on applying a family of finite difference methods for discretizing the spatial and time derivatives. The obtained system has been solved by two‐grid method, where the two‐grid method is used for solving the large‐sparse linear systems. Also, in the proposed method, the spectral radius with local Fourier analysis is calculated for different values of h and Δt. The numerical examples show the efficiency of this algorithm for solving the one‐dimensional and two‐dimensional Fitzhugh–Nagumo equations. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
7.
介绍了Rieffel定义的紧致量子度量空间与量子Gromov-Hausdorff距离和近来Latrémolière定义的量子Gromov-Hausdorff邻距,分别讨论了矩阵代数如何在这两种量子距离下收敛至球面. 相似文献
8.
Seakweng Vong Chenyang Shi Pin Lyu 《Numerical Methods for Partial Differential Equations》2017,33(6):2141-2158
In this article, we consider two‐dimensional fractional subdiffusion equations with mixed derivatives. A high‐order compact scheme is proposed to solve the problem. We establish a sufficient condition and show that the scheme converges with fourth order in space and second order in time under this condition.© 2017 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 33: 2141–2158, 2017 相似文献
9.
In this paper, in terms of the Fréchet normal cone, we establish exact separation results for finitely many disjoint closed sets in an Asplund space, which supplement the extremal principle and some fuzzy separation theorems. As an application, we provide a new optimality condition for a constraint optimization problem in terms of Fréchet subdifferential and Fréchet normal cone. 相似文献
10.
借助显式紧致格式和隐式紧致格式的思想,基于截断误差余项修正,并结合原方程本身,构造出了一种求解一维定常对流扩散反应方程的高精度混合型紧致差分格式.格式仅用到三个点上的未知函数值及一阶导数值,而一阶导数值利用四阶Pade格式进行计算,格式整体具有四阶精度.数值实验结果验证了格式的精确性和可靠性. 相似文献